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The nucleus for spherulitic growth is the single crystal in which a multilayered stack is formed, and each lamella extends to form a lamellar bril The at ribbonlike lamellar brils diverge, twist, and branch as they grow outward from the nucleus Growth occurs by chain folding with the polymer chain axes being perpendicular to the length of the lamellar bril The strength of polymers indicates that more than van der Waals forces hold lamellae together There are interlamellar or intercrystalline brils (also termed tie molecules) between the lamellar brils within a spherulite and between brils of different spherulites Some polymer molecules simultaneously participate in the growth of two or more adjacent lamellae and provide molecular links that reinforce the crystalline structure The chain axes of tie molecules lie parallel to the long axes of the link each link between lamellae is an extended-chain type of single crystal. birt data matrix Java Data Matrix Barcode Generator - BarcodeLib.com
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