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Table 58 U.S. Consumer Credit Commercial Bank Rates: 1972 1989

If one obtains a negative value of X n in the calculation, it.

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means that the system is past the gel point at that conversion. Second, the use of Eq. 2-139 allows one to calculate the critical extent of reaction at the gel point. Keep in mind that the extent of reaction calculated from Eq. 2-137 or 2-139 refers to the extent of reaction of the A functional groups (de ned as those groups not in excess). The extent of reaction of the B functional groups is rp or rpc. 2-10b Statistical Approach to Gelation: X w ! 1

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Whether or not wires touch each other within a circuit is pretty important to indicate unless, of course, you enjoy the fragrance of really hot semiconductors. Several conventions are used to depict whether wires that cross are connected to each other. Quite straightforward: If they re connected you ll see a dot at their junction. Simple enough, but if they re not connected you ll see one of two things. In the good ol days of electronics, when asbestos was used not only as insulation but also as chewing tobacco, unconnected wires were shown with one looping up over the other. Today you ll more often see their junction looking just the same as connected wires but without the dot. Both styles will be encountered as you read schematics. While the looping style may no longer be in vogue, the advantage is in its indication that the author was actually thinking at the moment the line was drawn and didn t just forget to dot the intersection.

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Shows how to merge PDF files with GemBox.Pdf .NET library in C# and VB.NET.

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Flory [1941, 1953] and Stockmayer [1943, 1952, 1953] used a statistical approach to derive an expression for predicting the extent of reaction at the gel point by calculating when X w approaches in nite size. The statistical approach in its simplest form assumes that the reactivity of all functional groups of the same type is the same and independent of molecular size. It is further assumed that there are no intramolecular reactions between functional groups on the same molecule. (These assumptions are also inherent in the use of Eqs. 2-137 through 2-143). For this derivation the branching coef cient a is de ned as the probability that a given functional group of a branch unit at the end of a polymer chain segment leads to another banch unit. For the polymerization of A with B and Af this corresponds to A B obtaining a chain segment of the type

LOAN SHARKS As in ancient Athens, and in all other periods of history, there has been no limit to the charges made by loan sharks. The better class of modern loan shark skirts the law by buying salaries or selling overpriced merchandise. A prevailing rate of 240%, running up to 1500% per annum, on loans of this type was suggested during the Great Depression by a survey in those

A A + B B + Af A(f 1) A(B BA A)nB BA A(f 1)

2-144

THE UNITED STATES IN THE TWENTIETH CENTURY: 1946 1990

where n may have any value from zero to in nity. The multifunctional monomer Af is considered a branch unit, while the segments between branch units are de ned as chain segments. The branch units occur on a polymer chain at the branch points (Fig. 1-2). In nite networks are formed when n number of chains or chain segments give rise to more than n chains through branching of some of them. The criterion for gelation in a system containing a reactant of functionality f is that at least one of the f 1 chain segments radiating from a branch unit will in turn be connected to another branch unit. The probability for this occurring is simply 1= f 1 and the critical branching coef cient ac for gel formation is

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